“调制剂诱导缺陷形成”策略构筑高稳定且多级孔结构的金属有机框架材料

来源 :中国化学会第八届全国配位化学会议 | 被引量 : 0次 | 上传用户:climb_climb
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  近二十年来,由于其结构的多样性、可调节性以及高的多孔性,金属有机框架(MOFs)材料在不同应用领域均显示出重要的应用潜力。然而,小的孔尺寸和低的稳定性等特性严重制约了其实际应用。
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金属有机框架(MOFs)是近二十年来发展最为迅猛的晶态多孔材料,在气体吸附、分离、发光、传感和催化领域具有潜在的应用前景。在众多的发光MOFs,其量子产率普遍偏低,一般都不超过20%,因此制备高亮发光的MOFs 已成为科研工作者的研究热点[1]。
金属有机配位聚合物因其有趣的结构性质和广泛的应用获得较高的关注。与发展较为成熟的过渡金属有机配位聚合物相比,锕系金属有机配位聚合物工作还相对落后。