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Rare earth mineral fast ion conductors of Li1+2x+3yAlxScyZnyTi2-x-2ySixP3-xO12 system based on LiTi2(PO4)3 were prepared by solid phase reaction at high temperature (1000~1300 ℃) for about 30 h using refined natural kaolinite and Sc2O3. The X-ray diffract