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The reaction of Co(OAc)2·4H2O with the Schiff base H2L in a methanol solution affords the red crystals of {[CoIIIL2]·[CoII(H2O)6]0.5·2.25H2O}4 1 (H2L = N-(2-hydroxyphenyl) sali-cylidenimine). The molecular and crystal structures were determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/n, C104H114Co6N8O37, Mr = 2421.61, a = 10.625(3), b = 16.335(4), c = 15.265(4) , β = 102.990(4)o, V = 2581.6(11) 3, Z = 1, Dc = 1.558 g/cm3, μ = 1.034 mm-1, F(000) = 1252, R = 0.0414 and wR = 0.1167 for 5889 reflections. The Co(III) atom is six-coordinated by two nitrogen atoms and four oxygen atoms of two tridentate L ligands. The abundant hydrogen bonding interactions extend the complex into a one-dimensional supra-molecular framework. The uncoordinated water molecules act as space-fillers and consolidate the whole architecture through the hydrogen bonding interactions.
The reaction of Co (OAc) 2.4H2O with the Schiff base H2L in a methanol solution affords the red crystals of {CoIIIL2] [CoII (H2O) 6] 0.5-2.25H2O} 4 1 (H2L = N- -hydroxyphenyl) sali-cylidenimine). The molecular and crystal structures were determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21 / n, C104H114Co6N8O37, Mr = 2421.61, a = 10.625 (3), b = 16.335 (4), c = 15.265 (4) β, β = 102.990 (4) o, V = 2581.6 (11) 3, Z = 1, Dc = 1.558 g / cm3, μ = (000) = 1252, R = 0.0414 and wR = 0.1167 for 5889 reflections. The Co (III) atom is six-coordinated by two nitrogen atoms and four oxygen atoms of two tridentate L ligands. a one-dimensional supra-molecular framework. The uncoordinated water molecules act as space-fillers and consolidate the whole architecture through the hydrogen bonding interactions.