,Highly efficient bifacial semitransparent perovskite solar cells based on molecular doping of CuSCN

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Coper thiocyanate (CuSCN) is generally considered as a very hopeful inorganic hole transport material (HTM) in semitransparent perovskite solar cells (ST-PSCs) because of its low parasitic absorption,high inherent stability,and low cost.However,the poor electrical conductivity and low work function of CuSCN lead to the insufficient hole extraction and large open-circuit voltage loss.Here,2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ) is employed to improve conductivity of CuSCN and band alignment at the CuSCN/perovskite (PVK) interface.As a result,the average power conversion efficiency (PCE) of PSCs is boosted by ≈ 11%.In addition,benefiting from the superior transparency of p-type CuSCN HTMs,the prepared bifacial semitransparent n-i-p planar PSCs demonstrate a maximum efficiency of 14.8% and 12.5% by the illumination from the front side and back side,respectively.We believe that this developed CuSCN-based ST-PSCs will promote practical applications in building integrated photovoltaics and tandem solar cells.
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