【摘 要】
：
A novel mixed-trib ridged dimolybdenum(Ⅰ) compound [Bu4N][Mo2(n-SPh)2(u-Cl)(CO)6] (1) has been synthesized from the reaction of Mo2 (CO)8 (SPh)2 with ButNCl.C
【机 构】
：
State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter
【出 处】
：
Chinese Journal of Chemistry
论文部分内容阅读
A novel mixed-trib ridged dimolybdenum(Ⅰ) compound [Bu4N][Mo2(n-SPh)2(u-Cl)(CO)6] (1) has been synthesized from the reaction of Mo2 (CO)8 (SPh)2 with ButNCl.Compound 1 was characterized by IR,UV-Vis and 1H,13C,95Mo NMR spectroscopic analyses.The electrochemical behavior was measured by cyclic voltammetry,indicating a quasi-reversible two-electron transfer in one step.The crystal structure determined by X-ray crystallography shows that 1 contains a [Mo2(u-S)2(u-Cl)]- core with a planar Mo2S2 unit and a Cl bridge.The Mo-Mo distance is 0.28709(7) nm,and the Mo-Cl-Mo angle is 66.44(4).A newface-sharing bioctahedral structure is discussed.
A Novel mixed-trib ridged dimolybdenum (I) compound [Bu4N] [Mo2 (n-SPh) 2 (u- Cl) (CO) 6] (1) has been synthesized from the reaction of Mo2 (CO) 2 with ButNCl.Compound 1 was characterized by IR, UV-Vis and 1H, 13C, 95Mo NMR spectroscopic analyzes. The electrochemical behavior was measured by cyclic voltammetry, indicating a quasi-reversible two-electron transfer in one step. Crystal The Mo-Mo distance is 0.28709 (7) nm, and the Mo-Mo crystal is a Mo2S2 unit Cl-Mo angle is 66.44 (4). A newface-sharing bioctahedral structure is discussed.
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