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The non-isothermal decomposition reaction of Nd[(C_5H_ 10NS_2)_3(C_ 12H_8N_2)] were carried out by means of TG-DTG and the thermal decomposition mechanism, and the associated kinetics was investigated. The kinetic parameters are obtained from an analysis of the TG-DTG curves at different heating rate by integral and differential methods. The most probable kinetic model function of the decomposition reaction is Maple Power of n=3/2, f(α)=2/3α -1/2 and the apparent activation energy E is 116.67 kJ·mol -1 and the pre-exponential factor lg[A/s -1] is 7.6891.
The non-isothermal decomposition reaction of Nd [(C_5H_10NS_2) _3 (C_12H_8N_2)] carried out by means of TG-DTG and the thermal decomposition mechanism, and associated kinetics was investigated. The kinetic parameters are obtained from an analysis of the TG-DTG curves at different heating rates by integral and differential methods. The most probable kinetic model function of the decomposition reaction is Maple Power of n = 3/2, f (α) = 2 / 3α -1/2 and the apparent activation energy E is 116.67 kJ · mol -1 and the pre-exponential factor lg [A / s -1] is 7.6891.