Study on the pyrolysis behavior of some glycosidic flavor precursors by on-line and off-line Py-GC-M

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  To develop thermal stable flavor, some glycosidic bond flavor precursors of β-D-glycosides were synthesized by the modified Koenigs-Knorr reaction.The glycosides were characterized by infrared spectroscopy(IR), liquid chromatography-mass spectrography-mass spectrography(LC-MS-MS), 1H NMR and 13C NMR.In order to investigate the pyrolysis behavior of the flavor precursors, the glycosides were pyrolysed at 200℃, 300℃, 400℃ in an on-line pyrolyser and in an off-line mode separately.Gas chromatography-mass spectrometry(GC-MS) was used for the qualitative and quantitative analysis of the pyrolysis products.Then the thermal degradation mechanism of glycosides was discussed according to the results.
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